Method of refining of scandium oxide from concentrates using solvent extraction

ABSTRACT

A method of selectively removing impurities from a scandium-containing feed solution includes contacting an aqueous scandium-containing solution with an organic solvent stream containing an extractant, thereby forming a loaded organic solvent stream containing the impurity or impurities while leaving the scandium in the raffinate. The aqueous stream containing the scandium is washed, diluted and has inorganic salts added before being contacted with a second organic solvent stream to extract the scandium selectively, and followed by stripping the scandium from the scandium-containing loaded organic extractant stream by adding oxalic acid to the loaded organic extractant stream to form scandium oxalate.

FIELD OF THE INVENTION

The present invention relates generally to selectively recoveringscandium from extractive metallurgy waste, and more particularly toextracting and recovering scandium from waste acid streams generatedfrom titanium processing.

BACKGROUND

Due to limitations in mining and availability, scandium is currentlyonly produced in small quantities. While the element occurs in manyores, it is only present in trace amounts; there are no known,easily-extractable deposits of minerals containing high scandiumcontent. Currently, only a few mines produce scandium, and in each caseit is made as a byproduct from the extraction of other elements and soldas scandium oxide.

In particular, scandium has gained importance for the use ofscandium-stabilized zirconia as a high efficiency electrolyte in solidoxide fuel cells. Applications of scandium also include use of scandiumoxide (Sc₂O₃) to make high-intensity discharge lamps, andscandium-aluminum alloys that are used for minor aerospace industrycomponents, baseball bats, and bicycle frames. As commercial uses forscandium continue to expand, there exists the need for the developmentof improved methods to selectively recover scandium from readilyavailable sources.

SUMMARY OF THE INVENTION

An embodiment relates to a method of selectively removing scandium froma scandium-containing feed solution including contacting an aqueousscandium-containing solution with a second organic solvent streamcomprising a second extractant, thereby forming a scandium-containingloaded organic solvent stream having at least a portion of the scandiumfrom the scandium-containing solution and stripping the scandium fromthe scandium-containing loaded organic extractant stream by addingoxalic acid to the loaded organic extractant stream to form scandiumoxalate.

Another embodiment relates to a method of selectively removing scandiumfrom an aqueous scandium-containing feed solution including selectivelyremoving zirconium from the aqueous scandium-containing solution bycontacting the aqueous scandium-containing solution with a first organicsolvent stream comprising a first extractant, the first extractantcomprising an amine compound and selectively removing scandium from theaqueous scandium-containing solution after the step of selectivelyremoving zirconium by contacting the aqueous scandium-containingsolution with a second organic solvent stream comprising a secondextractant to form a scandium-containing loaded organic solvent stream,the second extractant comprising an organo-phosphorous compound andstripping the scandium from the scandium-containing loaded organicextractant stream by forming scandium oxalate.

An embodiment relates to a method of selectively removing a metal froman aqueous feed solution including selectively removing zirconium fromthe aqueous feed solution using a first organic solvent and strippingthe zirconium from the first organic solvent with an aqueous HClsolution.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are incorporated herein and constitutepart of this specification, illustrate exemplary aspects of theinvention. Together with the general description given above and thedetailed description given below, the drawings serve to explain featuresof the invention.

FIG. 1A is a portion of a process flow diagram illustrating an overviewof the steps in a method of refining of scandium oxide from concentratesusing solvent extraction according to an embodiment.

FIG. 1B is another portion of the process flow diagram illustratingadditional steps that follow the steps in the method of the embodimentof FIG. 1A.

DETAILED DESCRIPTION

As used herein, selective removal of an ion or compound generally refersto methods to facilitate the removal of the ion or compound fromsolutions. As used herein, the selective removal of scandium generallyrefers to methods to facilitate the removal of scandium (III) ions(Sc³⁺) or scandium-containing compounds from a solution.

As used herein, solvent extraction refers to extracting a substance fromone liquid phase (e.g., an aqueous solution) into a different liquidphase (e.g., an organic solvent) based on the relative solubility of thesubstance in each of the phases.

As used herein, titanium processing refers to extraction or refinementof titanium products, such as titanium dioxide (TiO₂) (e.g., by thesulfate process or chloride process), titanium sponge, and/or othertitanium products for commercial use from titanium-containing ore. Forexample, titanium dioxide is commonly extracted from ilmenite using thesulfate method, which produces a waste stream containing dilute sulfuricacid. Another example is the extraction of titanium dioxide from rutileor leucoxene using the chloride method, which produces a waste streamcontaining hydrochloric acid. In an embodiment, the waste stream (e.g.,liquor) from titanium dioxide processing may be hydrolytic solution(i.e., dissolved ions in solution) that contains approximately 15-20mg/L scandium, with other impurities such as zirconium (Zr), titanium(Ti), iron (Fe) and silicon dioxide (SiO₂), In a preferred embodiment,scandium may be directly extracted from the effluent waste liquor fromtitanium dioxide processing. The embodiments described herein areequally applicable to artificially prepared waste streams that simulatethe waste liquor from titanium processing, and to other salt solutions.

Scandium oxide, and more particularly scandium (III) oxide, is describedherein as the end product of the various embodiment methods. However,scandium(III) oxide is given merely as an example, and the methodsdescribed herein may be used in the production of other useful products,including, but not limited to, non-stoichiometric scandium oxide,scandium(III) chloride (ScCl₃), scandium(III) hydroxide (Sc(OH)₃), andscandium(III) oxalate (Sc₂(C₂O₄)₃). These products are collectivelyreferred to herein as “scandium compound end products”.)

Methods for the selective recovery of scandium, e.g., scandium compoundend products, for example, in the form of scandium oxide from titaniumprocessing waste streams are provided. The steps of the variousembodiments may include: solvent extraction (e.g., cross-current solventextraction) to load at least one stage (e.g., multiple stages) of anorganic phase with scandium ions (e.g., Sc³⁺) from a solution; strippingscandium ions from the organic phase; precipitation of a scandiumoxalate product from the filtrate; and drying and calcination a productcontaining scandium oxide (e.g., Sc₂O₃). According to the preferredembodiments, byproducts may be recycled back for use in different stepsof the process, or may be converted back into a starting reactant foruse in a different step of the process.

A method for the selective recovery of scandium from a waste acid streamaccording to an embodiment is illustrated in FIGS. 1A and 1B. In method100, scandium may be removed in a multi-stage cross-current solventextraction process from a waste liquor generated during titanium dioxide(e.g., TiO₂) refinement by the sulfate method.

In the various embodiments, cross-current solvent extraction isperformed by feeding a scandium-containing stream and a solvent streaminto an extraction unit. In preferred embodiments, thescandium-containing stream may be an aqueous phase, i.e., a waste acidliquor stream containing scandium ions, and the solvent stream may be anorganic phase.

In a preferred embodiment, cross-current solvent extraction may beperformed as a multistage process using a cross-current array. Amultistage cross-current array may contain multiple extraction units,for example two to six, such as three extraction units in series. In anembodiment, the extraction units in an array may be mixing tanks orsettlers, or mixer-settler units. In another embodiment, extractionunits may be centrifugal extractors that mix and separate in the sameunit.

In steps 102 a-102 c, a waste acid stream 101 containing many species insolution, including scandium, may be contacted and mixed with anextractant and an organic liquid at a phase ratio of 1:2 to 1:50, suchas 1:25, organic to aqueous (O:A). The organic liquid may be, forexample, a high flash point kerosene (e.g., laboratory grade kerosene)or another organic with similar properties (e.g., hexane). In apreferred embodiment, an extractant is also mixed with the waste acidstream and the organic phase. The extractant may be one of a number ofcommercially available reagents. Examples of such extractants mayinclude, but are not limited to bis(2 ethylhexyl) hydrogen phosphate(DEHPA) (CAS Number 4971-47-5), and tributyl phosphate (TBP) (CAS Number126-73-8).

The extractant reacts with a portion of the scandium ions in the aqueousphase to form a Sc-extractant complex that is more soluble in theorganic liquid than in the aqueous phase. In a preferred multistagecross-current process, the aqueous raffinate 103 a, 103 b from oneextraction unit in steps 102 a-102 c is fed to the next unit as theaqueous feed, while multiple cross-current streams of the barren (i.e.,fresh or unloaded) organic phase 105 a-105 c are provided to extractionunits to contact the aqueous feed, without feeding the loaded organicinto the next extraction unit. Thus, barren organic phase is provided toeach unit, while the aqueous phase flows from one unit to the next inseries in the cross-current extraction process. Each successiveextraction stage removes a portion of the remaining scandium ions in theaqueous phase into the organic phase 107 a-107 c. In a preferredembodiment, solvent extraction may include three cross-current stages,steps 102 a-102 c. However, other embodiments may include more thanthree stages, or may include fewer than three stages. In contrast, in acounter-current extraction process, the loaded organic phase is providedfrom one extraction unit to the next unit in series in an oppositedirection to the aqueous phase flow between the units.

Thus, in an embodiment, the scandium-containing feed solution 101 iscontacted with a barren first solvent stream 105 a in a first stage 102a. The first solvent stream 105 a is loaded with at least a portion ofthe scandium from the feed solution. The loaded first solvent 107 a isseparated from the remaining scandium-containing feed solution 103 afrom the first stage 102 a.

The first stage is followed by contacting the remainingscandium-containing feed solution 103 a from the first stage 102 a witha barren second solvent stream 105 b in a second stage 102 b. The secondsolvent stream 105 b is loaded with at least a portion of the scandiumfrom the remaining scandium-containing feed 103 a from the first stage102 a. The loaded second solvent 107 b is separated from remainingscandium-containing feed solution 103 b from the second stage 103 b.

Then, in a third stage 102 c, the remaining scandium-containing feedsolution 103 b from the second stage 102 b is contacted with a barrenthird solvent stream 105 c. The third solvent stream 105 c is loadedwith at least a portion of the scandium from the remainingscandium-containing feed 103 b from the second stage 102 b. The loadedthird solvent 107 c is separated from the remaining scandium-containingfeed solution 103 c from the third stage 102 c.

This embodiment may include more than three stages described above. Thefirst, second and third stages 102 a-102 c in this embodiment may beperformed respectively in first, second, and third extraction units,connected in series to form a cross-current array.

At the end of steps 102 a-102 c, the spent aqueous solution 103 c may bescrubbed using, for example, a dual media filter or a coalescer, torecover any organic phase that was carried through the extraction, step104. The aqueous raffinate may be collected, for example, into a wasteholding tank, step 106. Any recovered organic phase can be recycled sothat it can be used in steps 105 a-105 c.

The cumulative loaded organic phase 107 from steps 102 a-102 c is thenpurified in a series of scrubbing steps. The scrubbing steps may also beconducted using a cross current process. Preferably, a zirconium scrubstep may be omitted between steps 102C and 110.

In step 110, the loaded organic 107 from steps 102 a-102 c may beprovided to a titanium scrubbing process. In an example embodiment,sulfuric acid (e.g., 0.5-5M H₂SO₄) and hydrogen peroxide (e.g., 2-10%,e.g., 5% H₂O₂) 113 may be used as scrubbing agents to remove titaniumimpurities 115. Other impurities that may be removed by further optionalscrubbing stages (not shown for clarity in FIG. 1A) may include, forexample, iron (Fe) and manganese (Mn).

The spent scrubbing agents containing the impurities 111, 115 from step110 may also contain recoverable, usable compounds. For example, one ofthe compounds that may be present in the spent sulfuric acid andhydrogen peroxide used for titanium scrubbing in step 110 is titaniumoxysulfate (TiOSO₄) 115. Titanium oxysulfate, which can be used as amordant in dyeing processes, may be recovered from the spent scrubbingagent and used and/or sold for use in a pigment plant.

In step 112, a strip solution 117 may be added to the purified loadedorganic phase 107P to unload scandium. The strip solution may be, forexample, a sodium hydroxide (NaOH) solution. Sc³⁺ ions may be unloadedfrom the organic phase 107P and into an aqueous phase 119 with Na⁺ andOH⁻, from which Sc(OH)₃ may precipitate out of solution. Strippingscandium from the organic phase 107P using a NaOH strip solution mayproceed according to the following reaction:

HSc(SO₄)₂.xHR+8NaOH→Sc(OH)₃↓+2Na₂SO₄+xNaR   (eq. 2).

In an embodiment, the unloaded organic (i.e., barren organic 121) liquidmay be recycled back to the extraction units to be incorporated in theorganic phase 105 a-105 c for the solvent extraction stages in steps 102a-102 c. Extractant 123 can be added to barren organic 121 and recoveredorganic from step 104 to form the organic phase 105 a-105 c. Sc(OH)₃ maybe separated from the aqueous solution 119 using any suitabletechniques. In an example embodiment, Sc(OH)₃ precipitate 125 may beseparated from the aqueous phase 119 in a clarifier. In anotherembodiment, a centrifuge may be used to separate the precipitatedSc(OH)₃ 125 from solution 119. In a preferred embodiment, the aqueoussolution 119 containing Sc(OH)₃ precipitate may be fed into a filter(e.g., a vacuum filter) to produce a filter cake of Sc(OH)₃ 125 in step116. The filtrate solution may be recovered in a tank, and, in step 118,sodium hydroxide 117 may be recycled back to the strip solution used instep 112 to unload scandium ions from the organic phase 107P. In anembodiment, the resulting filter cake may contain, for example, 10-90 wt% Sc(OH)₃, thereby yielding 5-50 wt % scandium. The components whichmake up the remainder of the resulting filter cake may be, for example,residual TiO₂, NaOH, iron, calcium and/or rare earth elements.

As illustrated in FIG. 1B, the remaining steps of the method may begrouped in two stages to aid in understanding of the method. The firststage, Stage 1, comprises solvent extraction of zirconium from anaqueous solution of the filter cake produced in step 116. The secondstage, Stage 2, comprises solvent extraction of scandium from theraffinate of Stage 1. The details of Stage 1 and Stage 2 are as follows.

In step 120 of Stage 1, the filter cake 125 formed in step 116 may beprovided from a concentrated scandium feed bin 116A into a leaching tanktogether with an acid 127 from an acid feed tank to leach and dissolvethe Sc containing filter cake. In an embodiment, a scandium containingconcentrate containing 5-50% (w/w) Sc on a dry basis may obtained from astream such as spent acid from a TiO₂ pigment plant. The leach solutionmay then be filtered in step 120 a, producing an outflow filtratesolution 129 with scandium ions as well as impurity ions such as Zr andTi. In an embodiment, the leaching acid 127 may be, but is not limitedto, hydrochloric acid (HCl) or sulfuric acid (H₂SO₄) to produce anacidic aqueous solution 129 at pH 0.1-1.0 containing up to 10 g/L Sc. Inan embodiment, the leach solution may include 5-10 g/L of Sc, 1-5 g/L ofZr, 1-5 g/L of Ti, 0.1-0.5 g/L of Fe and 0.1-0.8 g/L of Ca.

In step 122, the acidic aqueous filtrate solution 129 may be contactedwith an organic phase 124 in a zirconium solvent extraction process. Theorganic phase 124 may be an organic extractant comprising an amineextractant at 5-20% (v/v), such as 10% (v/v) concentration, in anorganic solvent, such as high flash point kerosene. The extractant maybe any compound that complexes with (i.e. binds to) Zr from the aqueousphase and returns into the organic phase. In a preferred embodiment, theextractant has an amine functional group and C5-C12 carbon chain. Zrbinds to the amine group. Preferably, the extractant does not bindto/complex with Sc. Preferably, the extractant is a straight chain aminewith C8-C10 in the alkyl group, (e.g. BASF Alamine® 336). In anembodiment, the organic phase may include a diluent and/or a modifier at5-20% (v/v), such as 10% (v/v) concentration. The modifier is anycompound that improves transport across the boundary between the aqueousand organic phases and aids in disengagement of the phases. That is, themodifier helps drops of organic phase located in the aqueous phase tocoalesce into the organic phase. Example modifiers include long chainalcohols, e.g. with a C8-C15 carbon chain. Suitable alcohols includeboth straight and branched alcohols. In a preferred embodiment, thealcohol comprises a carbon chain that includes 12 carbons, such astridecyl alcohol (e.g., Exxal™ 13). The diluent may be any material thatimproves the solubility of the organic extractant in the organic phase,such as kerosene or a dearomatized hydrocarbon fluid (e.g., Exxsol™D80). In an embodiment, the organic phase may have a composition of10-20% (v/v) amine, 5-15% (v/v) modifier and a balance of kerosene(65-85% (v/v)).

The solvent extraction in step 122 may be carried out, for example, inany suitable solvent extraction plant using one or more mixer-settlersin single or multi stage (such as 2-5, such as 3 stages) process. As aresult of step 122, the organic phase 124 may be loaded with zirconiumions from the filtrate solution 129, forming loaded organic phase 126.In an embodiment, step 122 results in removal of the Zr (e.g. 0.1 g/L orless Zr remains in the raffinate) from the filtrate solution 129 with nosignificant loss (e.g. less than 1% (M/M)) of Sc.

In step 128, the Zr can be stripped from the loaded organic phase 126with a strong acid 130 (e.g. 2-6M, such as 4M HCl) from an acid feedtank to allow recovery of pure ZrOCl₂ or ZrO₂ 131 from the acidic Zrstrip slurry or solution, if desired. The remaining organic phaseextractant 133 from step 128 may be regenerated in step 132 by treatingit with an alkaline solution 134 (e.g. 40-100 g/L Na₂CO₃, or 20-100 g/LNaOH) from a recycle tank to reactivate the amine containing organicphase 124 to recycle it to step 122 of Stage 1.

The aqueous raffinate 136 may be diluted by adding demineralized water,such as to a concentration of 2-4 g/L, such as 3g Sc/L of water in step175. Additionally, MgSO₄ may be added in step 175 to the aqueousraffinate 136, such as at about 0.5M concentration, to aid separation ofthe organic phase from the aqueous phase after mixing in the secondsolvent extraction 137. In an embodiment, the diluted aqueous raffinate176 provided to step 137 includes 1.0-5.0 g/L of Sc, 0.5-2.5 g/L of Ti,0.01-0.10 g/L of Zr, 0.05-0.25 g/L of Fe, 0.1-0.5 g/L of Ca and 6.0-20g/L of Mg. The pH may be 0.3-1.0.

In stage 2, in the second solvent extraction 137, Sc from the dilutedaqueous raffinate 176 is selectively extracted into an organic phase139. The organic phase 139 comprises an organophosphorus extractant(e.g. a dialkyl phosphinic acid extractant, such as Cytec Cyanex 272®,which comprises bis(2,4,4-trimethylpentyl) phosphinic acid) at 10-20%(v/v) concentration to form a loaded organic phase 140 from step 137. Inan embodiment, the organic phase 139 also includes a modifier (e.g.tri-butyl phosphate TBP) at 5-20% (v/v), such as 10% (v/v) concentrationin a diluent (e.g. Exxsol D80 or kerosene). The aqueous raffinate 138(e.g. sulfuric acid solution) from the second solvent extraction 137 maybe further treated for recycle, i.e. returned to the extraction plantfor recovery of any Sc remaining in the aqueous raffinate 138. Theloaded organic phase 140 from step 137 includes Ti and Sc which arecomplexed to the organic extractant.

The loaded organic phase 140 is then washed in step 177, such as with 15g/L NaCl solution 141, to remove any entrained aqueous phase along withiron, calcium and other un-complexed metals from the second solventextraction 137, forming a washed loaded organic phase 143. The loadedwash solution 142 may be further processed for reuse (e.g. to remove Ca,Fe, etc.).

The complexed scandium is stripped from the washed loaded organic phase143 in a Sc strip step 144. The Sc is stripped by contacting washedloaded organic phase 143 with a strip solution 158 comprising, forexample, 75-150 g/L, such as 100 g/L oxalic acid solution at 40-80° C.(typically 60° C.) to precipitate the Sc as scandium oxalate(Sc₂(C₂O₄)₃) in an aqueous suspension or mixture 145. In an embodiment,after mixing the washed loaded organic phase 143 with the strip solution158, the acidic aqueous mixture 145 is provided to a settler/separator147. The settled output 151 from the settler 147 is then provided to afilter 152 to separate the scandium oxalate 153 from the oxalic acidcontaining filtrate 154. The filtrate 154 may be recycled via a conduit157 for further use as a strip solution 158. This stream may bemonitored for buildup of impurities (e.g. Zr) and periodically a bleedstream may be treated to reduce the level of these in the circuit.

In step 155, the Sc₂(C₂O₄)₃ in the filtered scandium oxalate precipitate153 may be dried of excess moisture and calcined (i.e., heated toconvert Sc₂(C₂O₄)₃ to Sc₂O₃) at 700-800 degrees Celsius to obtain ascandium compound end product 156 (e.g., a scandium oxide solidcomposition) that has a composition of at least 99 wt %, such as around99 to 99.9 wt % scandium oxide.

In a Ti scrub and organic solution regeneration step 149, the complexedTi containing stripped organic solution 146 from step 144 is scrubbed toremove the co-extracted Ti by treating the stripped organic solution 146with an aqueous solution 148, e.g. 400-600 g/L, such as 500 g/L, H₂SO₄and 2-5% (v/v), such as 3% (v/v) H₂O₂, to remove the Ti. The resultingorganic phase 139 from step 149 can be recycled to the second solventextraction step 137. The loaded scrub solution 150 may be furtherprocessed for reuse (e.g., to remove Ti).

As is understood in the art, not all equipment or apparatuses are shownin the figures. For example, one of skill in the art would recognizethat various holding tanks and/or pumps may be employed in the presentmethod.

The foregoing method descriptions and the process flow diagrams areprovided merely as illustrative examples and are not intended to requireor imply that the steps of the various embodiments must be performed inthe order presented. As will be appreciated by one of skill in the artthe steps in the foregoing embodiments may be performed in any order.Words such as “then,” “next,” etc. are not intended to limit the orderof the steps; these words are simply used to guide the reader throughthe description of the methods. Although process flow diagrams maydescribe the steps as a sequential process, many of the steps can beperformed in parallel or concurrently.

Any reference to claim elements in the singular, for example, using thearticles “a,” “an” or “the” is not to be construed as limiting theelement to the singular.

The preceding description of the disclosed embodiments is provided toenable any person skilled in the art to make or use the presentinvention. Various modifications to these embodiments will be readilyapparent to those skilled in the art, and the generic principles definedherein may be applied to other embodiments without departing from thespirit or scope of the invention. Thus, the present invention is notintended to be limited to the embodiments shown herein but is to beaccorded the widest scope consistent with the following claims and theprinciples and novel features disclosed herein.

1. A method of selectively removing scandium from a scandium-containingfeed solution, comprising: contacting an aqueous scandium-containingsolution with a second organic solvent stream comprising a secondextractant, thereby forming a scandium-containing loaded organic solventstream having at least a portion of the scandium from thescandium-containing solution; and stripping the scandium from thescandium-containing loaded organic extractant stream by adding oxalicacid to the loaded organic extractant stream to form scandium oxalate.2. The method of claim 1, wherein the second extractant comprises anorganophosphorus compound.
 3. The method of claim 2, wherein the aqueousscandium-containing solution further comprises MgSO₄.
 4. The method ofclaim 1, wherein the second organic solvent stream further comprises amodifier and a diluent.
 5. The method of claim 1, further comprisingcalcining the scandium oxalate to form Sc₂O₃.
 6. The method of claim 1,further comprising scrubbing the loaded organic extractant stream afterstripping the scandium to remove titanium from the loaded organicscandium-containing extract.
 7. The method of claim 1, furthercomprising selectively removing zirconium from the aqueousscandium-containing solution by contacting the aqueousscandium-containing solution with a first organic solvent streamcomprising a first extractant comprising an amine compound, prior tocontacting the aqueous scandium-containing solution with the secondorganic solvent stream.
 8. A method of selectively removing scandiumfrom an aqueous scandium-containing feed solution, comprising:selectively removing zirconium from the aqueous scandium-containingsolution by contacting the aqueous scandium-containing solution with afirst organic solvent stream comprising a first extractant, the firstextractant comprising an amine compound; and selectively removingscandium from the aqueous scandium-containing solution after the step ofselectively removing zirconium by contacting the aqueousscandium-containing solution with a second organic solvent streamcomprising a second extractant to form a scandium-containing loadedorganic solvent stream, the second extractant comprising anorgano-phosphorous compound; and stripping the scandium from thescandium-containing loaded organic extractant stream by forming scandiumoxalate.
 9. The method of claim 8, wherein the first organic solventstream comprises at least one of a first modifier and a first diluentand the second organic solvent stream comprises at least one of a secondmodifier and a second diluent.
 10. The method of claim 9, wherein thefirst modifier comprises an alcohol comprising a C8-C15 carbon chain,the first and second diluent comprises kerosene or a dearomatizedhydrocarbon fluid.
 11. The method of claim 10, wherein the firstmodifier comprises a tridecyl alcohol and the second modifier comprisestributyl phosphate.
 12. The method of claim 8, wherein stripping thescandium comprises adding oxalic acid to the scandium containing loadedorganic extractant stream to form scandium oxalate.
 13. The method ofclaim 12, further comprising washing and filtering the scandium oxalateand calcining the scandium oxalate to form scandium oxide.
 14. Themethod of claim 8, further comprising stripping the zirconium from thefirst organic solvent with an aqueous HCl solution.
 15. The method ofclaim 14, further comprising reactivating the amine compound by treatingthe amine compound with an alkaline solution.
 16. The method of claim 8,further comprising selectively removing titanium from thescandium-containing loaded organic extractant stream after stripping thescandium.
 17. The method of claim 8, further comprising diluting theaqueous scandium-containing solution prior to selectively removing thescandium.
 18. The method of claim 12, wherein the second extractantcomprises bis(2,4,4-trimethylpentyl) phosphinic acid.
 19. The method ofclaim 18, wherein the first extractant comprises a straight chainternary amine with C8-C10 in an alkyl group.
 20. A method of selectivelyremoving a metal from an aqueous feed solution, comprising: selectivelyremoving zirconium from the aqueous feed solution using a first organicsolvent; and stripping the zirconium from the first organic solvent withan aqueous HCl solution.
 21. The method of claim 20, wherein selectivelyremoving zirconium from the aqueous feed solution comprises contactingthe aqueous feed solution with a first organic solvent stream comprisinga first extractant, the first extractant comprising an amine compound.22. The method of claim 21, further comprising after selectivelyremoving zirconium: selectively removing scandium and titanium from theaqueous feed solution by reacting the aqueous feed solution with asecond organic solvent stream comprising a second extractant to form ascandium and titanium-containing loaded organic solvent stream; andstripping the scandium from the scandium and titanium-containing loadedorganic extractant stream by forming scandium oxalate.
 23. The method ofclaim 22, further comprising prior to selectively removing zirconium,removing titanium from the aqueous feed solution using cross currentextraction.